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1.
The Harlem coal is postulated to have been deposited in raised-bog settings. It was initially deposited as low-sulfur peat, but groundwater of a later origin altered portions of it to high-sulfur coal. The total sulfur content of 172 samples from 31 locations on a moisture- and ash-free basis have a quadrimodal distribution with two major modes at 0.75% S and 2.0%S. Multiple sampling and analyses at specific mine sites indicate that the addition of sulfur of a later origin occurred either laterally adjacent to sandstone channels or vertically adjacent to faults. Significant sulfur addition also occurred above clay partings at these sites. The original low-sulfur nature is preserved where the coal bed is isolated from descending groundwater by a thick impervious layer. Trace-element analyses show high concentrations of mobile elements such as Na and Mn in the high-sulfur coals.  相似文献   
2.
The effects of climate change and population growth in recent decades are leading us to consider their combined and potentially extreme consequences, particularly regarding hydrological processes, which can be modeled using a generalized extreme value (GEV) distribution. Most of the GEV models were based on a stationary assumption for hydrological processes, in contrast to the nonstationary reality due to climate change and human activities. In this paper, we present the nonstationary generalized extreme value (NSGEV) distribution and use it to investigate the risk of Niangziguan Springs discharge decreasing to zero. Rather than assuming the location, scale, and shape parameters to be constant as one might do for a stationary GEV distribution analysis, the NSGEV approach can reflect the dynamic processes by defining the GEV parameters as functions of time. Because most of the GEV model is designed to evaluate maxima (e.g. flooding, represented by positive numbers), and spring discharge cessation is a ?minima’, we deduced an NSGEV model for minima by applying opposite numbers, i.e. negative instead of positive numbers. The results of the model application to Niangziguan Springs showed that the probability of zero discharge at Niangziguan Springs will be 1/80 in 2025, and 1/10 in 2030. After 2025, the rate of decrease in spring discharge will accelerate, and the probability that Niangziguan Springs will cease flowing will dramatically increase. The NSGEV model is a robust method for analysing karst spring discharge. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
3.
ABSTRACT

Despite extensive studies being devoted to housing affordability in Australia, few have investigated housing affordability at a disaggregated level. This is in spite of the fact that there are existing socio-economic and demographic disparities across different regions of a city. This study aims to fill this gap by examining housing affordability in Sydney, a city that is characterised by diverse demographic and socio-economic mix, from a sub-city perspective. Two dimensions of affordability are assessed from 1991 to 2016: entry-level and ongoing housing affordability. The study finds that entry-level housing remains extremely unaffordable in all regions of Greater Sydney, although the level of unaffordability varies across regions. Specifically, the deterioration in housing affordability is more obvious in low-income regions such as Western Sydney. In addition, the ongoing housing affordability of those who have entered the market improves considerably within 5–10 years, although there are significant variations between different regions. Importantly, residents in low-income regions such as Western Sydney take a longer period to improve their ongoing affordability. The findings of differential geography of housing affordability have some profound policy implications. Policymakers should consider the disparities across different regions by formulating a more targeted and regionally balanced housing policy.  相似文献   
4.
Karst aquifers are well known for their intricate stratigraphy and geologic structures, which make groundwater characterization challenging because flowpaths and recharge sources are complex and difficult to evaluate. Geochemical data, collected from ten closely spaced production wells constructed in two karst aquifers (Bangor Limestone (Mb) and Tuscumbia Limestone/Fort Payne Chert (Mftp)) in Trussville, north‐central Alabama, illustrate two distinctive groundwater end‐members: (1) higher major ion, dissolved inorganic carbon, conductivity, alkalinity concentrations, heavier δ13C ratios (max: −10.2 ± 0.2‰ Vienna Pee Dee Belemnite (PDB)) and lower residence times (mean: 19.5 ± 2 years, n = 2) of groundwater in the Mb aquifer and (2) lower constituent concentrations, lighter δ13C ratios (min: −13.4 ± 0.2‰ PDB) and longer residence times of groundwater (mean: 23.6 ± 2 years, n = 4) in the Mftp aquifer. Summer and fall data and the binary mixing model show aquifer inter‐flow mixing along solution fractures and confirms the distinctive groundwater geochemistry of the two aquifers. Lowering of static water levels over the summer (drawdown from 2 to 5.2 m) leads to more reducing groundwater conditions (lower Eh values) and slightly enriched δ18O and δD ratios during the fall [δ18O: −4.8 ± 0.1 to −5.4 ± 0.1‰ Vienna Standard Mean Oceanic Water (VSMOW), n = 9; δD: −25.4 ± 1 to −27.4 ± 1‰ VSMOW, n = 9] when compared with summer season samples (δ18O: −5.1 ± 0.1 to −5.7 ± 0.1‰ VSMOW, n = 11; δD: −25.0 ± 1 to −30.6 ± 1‰ VSMOW, n = 11). GIS analyses confirm the localized origin of recharge to the investigated aquifers. The combination of GIS, field parameters and geochemistry analyses can be successfully used to identify recharge sources, evaluate groundwater flow and transport pathways and to improve understanding of how groundwater withdrawals impact the sustainability and susceptibility to contamination of karst aquifers. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
5.
The traditional hydrological time series methods tend to focus on the mean of whichever variable is analysed but neglect its time‐varying variance (i.e. assuming the variance remains constant). The variances of hydrological time series vary with time under anthropogenic influence. There is evidence that extensive well drilling and groundwater pumping can intercept groundwater run‐off and consequently induce spring discharge volatility or variance varying with time (i.e. heteroskedasticity). To investigate the time‐varying variance or heteroskedasticity of spring discharge, this paper presents a seasonal autoregressive integrated moving average with general autoregressive conditional heteroskedasticity (SARIMA‐GARCH) model, whose the SARIMA model is used to estimate the mean of hydrological time series, and the GARCH model estimates its time‐varying variance. The SARIMA‐GARCH model was then applied to the Xin'an Springs Basin, China, where extensive groundwater development has occurred since 1978 (e.g. the average annual groundwater pumping rates were less than 0.20 m3/s in the 1970s, reached 1.20 m3/s at the end of the 1980s, surpassed 2.0 m3/s in the 1990s and exceeded 3.0 m3/s by 2007). To identify whether human activities or natural stressors caused the heteroskedasticity of Xin'an Springs discharge, we segmented the spring discharge sequence into two periods: a predevelopment stage (i.e. 1956–1977) and a developed stage (i.e. 1978–2012), and set up the SARIMA‐GARCH model for the two stages, respectively. By comparing the models, we detected the role of human activities in spring discharge volatility. The results showed that human activities caused the heteroskedasticity of the Xin'an Spring discharge. The predicted Xin'an Springs discharge by the SARIMA‐GARCH model showed that the mean monthly spring discharge is predicted to continue to decline to 0.93 m3/s in 2013, 0.67 m3/s in 2014 and 0.73 m3/s in 2015. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
6.
The geochemical classification proposed by Goldschmidt was based on meteoritic analysis and elemental partition in blast furnace. There are many surprises when applied to the discussion of natural occurrences. A modified classification of elements based on basic chemical properties and their occurrences. A modified classification of elements based on basic chemical properties and their occurrences in nature is, therefore, proposed for students learning geochemistry and geologists working in the field. Elements are classified into six groups including lithophile, oxyphile, siderophile, chalcophile, biophile, and atmophile elements. Five terms are taken from Goldshcmidt's original classification. Oxyphile is a new term.  相似文献   
7.
8.
The study on the hydraulic properties of coastal aquifers has significant implications both in hydrological sciences and environmental engineering. Although many analytical solutions are available, most of them are based on the same basic assumption that assumes aquifers extend landward semi‐infinitely, which does not necessarily reflect the reality. In this study, the general solutions for a leaky confined coastal aquifer have been developed that consider both finitely landward constant‐head and no‐flow boundaries. The newly developed solutions were then used to examine theoretically the joint effects of leakage and aquifer length on hydraulic head fluctuations within the leaky confined aquifer, and the validity of using the simplified solution, which assumes the aquifer is semi‐infinite. The results illustrated that the use of the simplified solution may cause significant errors, depending on joint effects of leakage and aquifer length. A dimensionless characteristic parameter was then proposed as an index for judging the applicability of the simplified solution. In addition, practical application of the general solution for the constant‐head inland boundary was used to characterize the hydraulic properties of a leaky confined aquifer using the data collected from a field site at the Seine River estuary, France, and the versatility of the general solution was further justified.  相似文献   
9.
This paper discusses some previous, and presents some new experimental results on wave transmission oversubmerged breakwaters. The objective of this study is to evaluate wave transmission coefficient and develop two-dimensional (2D) model as an improvement to the existing wave transmission coefficient models. Factors which affect wave transmission over submerged breakwaters are discussed through series of laboratory experiments. Basic recommendations for evaluation and design of submerged rubble-monud breakwaters are presented.From the test results, calculation formula of wave transmission coefficient is proposed.  相似文献   
10.
This study proposes a sediment‐budget model to predict the temporal variation of debris volume stored in a debris‐flow prone watershed. The sediment‐budget is dominated by shallow landslides and debris outflow. The basin topography and the debris volume stored in the source area of the debris‐flow prone watershed help evaluating its debris‐flow susceptibility. The susceptibility model is applied to the Tungshih area of central western Taiwan. The importance of the debris volume in predicting debris‐flow susceptibility is reflected in the standardized coefficients of the proposed statistical discriminant model. The high prediction rate (0·874) for the occurrence of debris flows justifies the capability of the proposed susceptibility models to predict the occurrence of debris flows. This model is then used to evaluate the temporal evolution of the debris‐flow susceptibility index. The analysis results show that the numbers of watershed which are classified as a debris‐flow group correspond well to storage of sediment at different time periods. These numbers are 10 before the occurrence of Chi‐Chi earthquake, 13 after the occurrence of Chi‐Chi earthquake, 16 after the occurrence of landslides induced by Typhoon Mindulle (Typhoon M), and 14 after the occurrence of debris flows induced by Typhoon M. It indicates that the occurrence of 7·6 Chi‐Chi earthquake had significant impact on the debris flow occurrence during subsequent typhoons. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   
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